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Q.

Which of the following complexes shows optical isomerism?

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a

$cis [Co (en)_{2} {Cl}_{2}] Cl$

b

$[Co {({NH}_{3})}_{3} {Cl}_{3}]$

c

$trans [Co (en)_{2} {Cl}_{2}] Cl$

d

$[Co {({NH}_{3})}_{4} {Cl}_{2}] Cl$

answer is A.

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Detailed Solution

The complex $cis - [M (AA)_{2} a_{2}]$ has no plane of symmetry or centre of symmetry and is thus an optically active. Its two isomers are:

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