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Which of the following complexes shows optical isomerism?

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a
 cis Co(en)2Cl2Cl
b
 trans Co(en)2Cl2Cl
c
CoNH34Cl2Cl
d
CoNH33Cl3

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detailed solution

Correct option is A

The complex  cis M(AA)2a2 has no plane of symmetry or centre of symmetry and is thus an optically active. Its two isomers are:

 

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