Which of the following has maximum angular volume of orbital containing lone pair?

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${PCl}_{3}$

${PH}_{3}$

${NF}_{3}$

${NH}_{3}$

answer is A.

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Detailed Solution

${NF}_{3}$ has maximum angular volume of orbital contain lone pair compare to the other compound. NH3 has trigonal pyramidal geometry with bond angle 107°. Hence the correct option is A.

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