Which of the following liquid pairs shows a positive deviation from Raoult’s law?

Which of the following liquid pairs shows a positive deviation from Raoult's law?

  1. A

    water-hydrochloric acid

  2. B

    benzene-methanol

  3. C

    water-nitric acid

  4. D

    acetone-chloroform

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    Solution:

    The molecular interactions between benzene and methanol are weaker than those existing between benzene and benzene, and methanol and methanol. Consequently, the solution will exhibit positive deviations from Raoult's law.

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