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Which of the following liquid pairs shows a positive deviation from Raoult's law?

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a
water-hydrochloric acid
b
benzene-methanol
c
water-nitric acid
d
acetone-chloroform

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detailed solution

Correct option is B

The molecular interactions between benzene and methanol are weaker than those existing between benzene and benzene, and methanol and methanol. Consequently, the solution will exhibit positive deviations from Raoult's law.

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