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Which of the following orders is true regarding the boiling point of organic substances?

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{CH}_{3} COCl > {CH}_{3} COOH > {({CH}_{3} CO)}_{2} O

{CH}_{3} COCl < {CH}_{3} COOH < {({CH}_{3} CO)}_{2} O

{CH}_{3} COCl > {CH}_{3} COOH < {({CH}_{3} CO)}_{2} O

{CH}_{3} COCl < {CH}_{3} COOH > {({CH}_{3} CO)}_{2} O

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detailed solution

Correct option is B

${CH}_{3} COCl$ does not involve hydrogen bonding. Its boiling point is lesser than ${CH}_{3} COOH$ . The boiling point of the latter is lesser than that of ${({CH}_{3} CO)}_{2} O$ due to larger molar mass of ${({CH}_{3} CO)}_{2} O$ .

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