Which of the following set of overlap cannot provideπ-bond formation?

Which of the following set of overlap cannot provide $π$ -bond formation?

A
3d and 2p
B
2p and 3p
C
2p and 2p
D
3p and ls

Solution:

Since the s orbital by nature is spherical, $π$ - bonds cannot be formed because it can only accomplish head-on overlap.

Hence,3p and 1s set of overlap cannot provide $π$ -bond formation.

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