Q.

Which of the following solute will have minimum value of van 't Hoff factor?

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a

0.1 molal solution of benzoic acid in benzene

b

0.1 molal solution of acetic acid in water

c

0.1 molal solution of sodium chloride in water

d

0.1 molal solution of glucose in water

answer is B.

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Detailed Solution

Benzoic acid in benzene dimerises and hence its van 't Hoff factor is 1/2 which will be minimum amongs other values.

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