Which of the following statements regarding equilibrium constant of a reaction is correct?

Which of the following statements regarding equilibrium constant of a reaction is correct?

  1. A

    It increases linearly with increasing T

  2. B

    It increases linearly with increasing 1/T.

  3. C

    It increases exponentially with increase in temperature for an exothermic reaction

  4. D

    It increases exponentially with increase in temperature for an endothermic reaction

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    Solution:

    The variation  Keq is lnKeq=ΔrHT+ constant  or Keq=AeΔrH/T

    For endothermic reactions, ΔrH is positive and thus Keq increases exponentially with increase in temperature.

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