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Q.

Which one of the following complexes will consume more equivalents of aqueous solution of AgNO3?AgNO3

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a

CrH2O5ClCl2

b

Na3CrCl6

c

Na2CrCl5H2O

d

CrH2O6Cl3

answer is D.

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Detailed Solution

The anion Cl outside the coordination sphere gets precipitated with AgNO3. In the choice d, there are three chloride ions and thus will consume more equivalents of aqueous solution of AgNO3.

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