Which one of the following complexes will consume more equivalents of aqueous solution of AgNO3?AgNO3

Which one of the following complexes will consume more equivalents of aqueous solution of AgNO3?AgNO3

  1. A

    Na2CrCl5H2O

  2. B

    Na3CrCl6

  3. C

    CrH2O5ClCl2

  4. D

    CrH2O6Cl3

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    Solution:

    The anion Cl outside the coordination sphere gets precipitated with AgNO3. In the choice d, there are three chloride ions and thus will consume more equivalents of aqueous solution of AgNO3.

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