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Q.

Which one of the following species will have maximum bond dissociation energy?

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a

C2

b

C2+

c

C2

d

C22

answer is D.

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Detailed Solution

C2  (8 electrons); KK(σ2s)2(σ2s)2π2px2π2py2 Bond order =(62)/2=2

C2+ (7 electrons);  Bond order =(52)/2=11/2

C2 (9 electrons);  KK(σ2s)2(σ2s)2π2px2π2py2σ2py1 Bond order =(72)/2=212

C22 -(10 electrons);   Bond order =(82)/2=3

Larger the bond order, larger the dissociation energy.

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