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Q.
The general electronic configuration of f-block elements is
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a
(n-2)f1-14 (n-1)d0–1 ns2.
b
c
d
answer is B.
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Detailed Solution
The general electronic configuration of f block elements describes the distribution of electrons in the orbitals of the lanthanides and actinides. These elements are characterized by the gradual filling of the f orbitals. Below is a detailed explanation to understand the electronic configuration:
1. Identifying the Block
The f-block elements include the lanthanides and actinides, where electrons are progressively added to the f orbitals. These orbitals are part of the inner electron shells, making the general electronic configuration of f block elements unique compared to other blocks.
2. Understanding the Orbital Filling
The f orbitals consist of seven subshells, each capable of holding two electrons. Thus, the maximum electron capacity for the f orbitals is 14. The filling of these orbitals occurs two energy levels below the outermost shell.
3. General Configuration of f-Block Elements
The general electronic configuration of f block elements is written as:
(noble gas) n-2 f0-14 n-1 d0-1 ns2
Here:
- (noble gas): Represents the electron configuration of the closest noble gas preceding the element.
- n-2 f0-14: Indicates that electrons are added to the f orbitals two energy levels below the outermost shell.
- n-1 d0-1: Represents the possible presence of electrons in the d orbitals, one energy level below the outermost shell.
- ns2: Refers to the two electrons in the outermost s orbital.
4. Key Features of the Configuration
- The f orbitals are part of the inner electron shell, shielded by the outer s and p orbitals.
- The general electronic configuration of f block elements reflects their complex behavior due to the unique arrangement of electrons.
- The lanthanides involve the filling of 4f orbitals, while the actinides involve the 5f orbitals.
5. Practical Summary
The general electronic configuration of f block elements can be summarized as:
(noble gas) n-2 f0-14 n-1 d0-1 ns2
This configuration is critical to understanding the chemical and physical properties of the lanthanides and actinides.
Conclusion
The general electronic configuration of f block elements plays a significant role in defining the unique properties of these elements. Understanding this configuration helps explain their reactivity, magnetic behavior, and complex formation tendencies.