Q.

The general electronic configuration of f-block elements is

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a

(n-2)f1-14 (n-1)d0–1 ns2.

b

ns2nd0,1nf114

c

ns2(n1)d0,1(n1) f114

d

ns2 np6(n1)d1(n2) f114

answer is B.

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Detailed Solution

The general electronic configuration of f block elements describes the distribution of electrons in the orbitals of the lanthanides and actinides. These elements are characterized by the gradual filling of the f orbitals. Below is a detailed explanation to understand the electronic configuration:

1. Identifying the Block

The f-block elements include the lanthanides and actinides, where electrons are progressively added to the f orbitals. These orbitals are part of the inner electron shells, making the general electronic configuration of f block elements unique compared to other blocks.

2. Understanding the Orbital Filling

The f orbitals consist of seven subshells, each capable of holding two electrons. Thus, the maximum electron capacity for the f orbitals is 14. The filling of these orbitals occurs two energy levels below the outermost shell.

3. General Configuration of f-Block Elements

The general electronic configuration of f block elements is written as:

    (noble gas) n-2 f0-14 n-1 d0-1 ns2    

Here:

  • (noble gas): Represents the electron configuration of the closest noble gas preceding the element.
  • n-2 f0-14: Indicates that electrons are added to the f orbitals two energy levels below the outermost shell.
  • n-1 d0-1: Represents the possible presence of electrons in the d orbitals, one energy level below the outermost shell.
  • ns2: Refers to the two electrons in the outermost s orbital.

4. Key Features of the Configuration

  • The f orbitals are part of the inner electron shell, shielded by the outer s and p orbitals.
  • The general electronic configuration of f block elements reflects their complex behavior due to the unique arrangement of electrons.
  • The lanthanides involve the filling of 4f orbitals, while the actinides involve the 5f orbitals.

5. Practical Summary

The general electronic configuration of f block elements can be summarized as:

    (noble gas) n-2 f0-14 n-1 d0-1 ns2    

This configuration is critical to understanding the chemical and physical properties of the lanthanides and actinides.

Conclusion

The general electronic configuration of f block elements plays a significant role in defining the unique properties of these elements. Understanding this configuration helps explain their reactivity, magnetic behavior, and complex formation tendencies.

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