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Benzene

By Ankit Gupta

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Updated on 17 Apr 2025, 11:17 IST

Benzene is one of the most important chemicals in the world. It is used in making many everyday products and is studied a lot in chemistry. In this article, we will explain benzene, its properties, uses, and details like the benzene formula, benzene structure, molar mass of benzene, molecular mass of benzene, and molecular weight of benzene. We will use simple words so that everyone can understand.

Benzene

What is Benzene?

Benzene is an organic chemical compound. It is a clear, colorless liquid that smells sweet and strong. Benzene is very important because it is used to make plastics, rubbers, dyes, detergents, and many other products. Even though it is useful, benzene is also dangerous because it is poisonous and can cause cancer.

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Benzene is found naturally in volcanoes and forest fires. It is also found in crude oil, gasoline, and cigarette smoke.

Do Check: Urea

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Benzene Formula

The benzene formula is C6H6. This means that benzene is made of six carbon atoms and six hydrogen atoms. The benzene formula is simple but very special because it shows that the carbon and hydrogen atoms are arranged in a ring.

PropertyValue
Chemical NameBenzene
Benzene FormulaC6H6
Number of Carbon Atoms6
Number of Hydrogen Atoms6

Benzene Structure

The benzene structure is very unique. Benzene has a ring structure where six carbon atoms are linked together in a hexagon shape. Each carbon atom is attached to one hydrogen atom.

Benzene

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In the benzene structure, there are alternating single and double bonds between the carbon atoms. But scientists found that these bonds are actually equal. The electrons in the bonds move freely around the ring. This is called "resonance." Resonance makes benzene very stable.

Here is a simple way to imagine the benzene structure:

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  • Six carbon atoms form a ring.
  • Each carbon atom is bonded to one hydrogen atom.
  • Bonds between carbon atoms are not simple single or double bonds but are shared equally.

Do Check: Reactivity Series

Important Properties of Benzene

Here are some important properties of benzene:

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PropertyDetail
AppearanceColorless liquid
SmellSweet and strong
Density0.8765 g/cm³
Boiling Point80.1°C (176.2°F)
Melting Point5.5°C (41.9°F)
SolubilityInsoluble in water, soluble in alcohol and ether
FlammabilityHighly flammable

Molar Mass of Benzene

The molar mass of benzene is the mass of one mole of benzene molecules. The molar mass of benzene is 78.11 grams per mole (g/mol).

To calculate the molar mass of benzene:

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  • Carbon atomic mass = 12.01 g/mol
  • Hydrogen atomic mass = 1.008 g/mol

Molar mass = (6 × 12.01) + (6 × 1.008) = 72.06 + 6.048 = 78.108 g/mol

Thus, the molar mass of benzene is about 78.11 g/mol.

ElementNumber of AtomsAtomic Mass (g/mol)Total Mass (g/mol)
Carbon (C)612.0172.06
Hydrogen (H)61.0086.048
Total  78.108

Molecular Mass of Benzene and Molecular Weight of Benzene

The molecular mass of benzene and the molecular weight of benzene are often used to mean the same thing. Both describe the mass of one molecule of benzene compared to the mass of a carbon-12 atom.

  • The molecular mass of benzene = 78.11 amu (atomic mass units)
  • The molecular weight of benzene = 78.11

Thus, the molecular mass of benzene and the molecular weight of benzene are both 78.11.

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Do Check: Isomerism

History of Benzene

Benzene was discovered in 1825 by Michael Faraday. Later, in 1865, the scientist August Kekulé explained the ring structure of benzene. He said that benzene is made of six carbon atoms arranged in a hexagon.

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His idea helped scientists understand the special stability of benzene.

Resonance in Benzene

Resonance is very important in benzene. Because of resonance, the electrons are shared equally among the six carbon atoms. This makes the benzene structure very stable and strong.

Without resonance, benzene would react like other molecules with double bonds. But because of resonance, benzene behaves very differently and does not react easily.

Aromaticity of Benzene

Benzene is an "aromatic" compound. Aromatic compounds are molecules that are very stable and have special electron arrangements.

Benzene follows Huckel's Rule for aromaticity:

  • It is cyclic (forms a ring).
  • It is planar (flat shape).
  • It has 6 π electrons (4n + 2 rule, where n=1).

Because of these properties, benzene is highly stable and behaves differently from other compounds.

Do Check: Acetaldehyde

How is Benzene Made?

Benzene is made in industries through several methods:

  1. Catalytic Reforming: Changing the structure of hydrocarbons.
  2. Steam Cracking: Breaking down larger hydrocarbons by heating.
  3. Toluene Hydrodealkylation: Removing side groups from toluene.
MethodProcess
Catalytic ReformingConverts naphtha into benzene using catalysts
Steam CrackingBreaks large hydrocarbons to form benzene
Toluene HydrodealkylationConverts toluene into benzene by removing side chains

Uses of Benzene

Benzene is used in many industries because it is very useful. Some uses are:

  • Making plastics like polystyrene.
  • Making synthetic fibers like nylon.
  • Producing rubber for tires.
  • Manufacturing detergents and cleaning products.
  • Making dyes and paints.
  • Creating pesticides and other chemicals.

Although benzene is very useful, workers must handle it carefully because of its harmful effects.

Health Effects of Benzene

Even though benzene is helpful in industries, it is very dangerous to human health. Long exposure to benzene can cause serious diseases.

Short-term exposure to benzene can cause:

  • Dizziness
  • Headaches
  • Sleepiness
  • Rapid heartbeat

Long-term exposure can lead to:

  • Anemia
  • Damage to bone marrow
  • Leukemia (a type of cancer)

Thus, it is important to use safety measures while handling benzene.

FAQs on Benzene

Who found the structure of benzene?

Friedrich August Kekulé.

List any 3 food items containing benzene.

Pineapple Crush, Monster Light Cranberry Juice Cocktail, Aquacal Strawberry Flavored Water Beverage.

What are the three critical steps to produce benzene industrially?

Catalytic reforming, Toluene hydrodealkylation, Steam cracking.

Briefly explain the shape of benzene.

Planar hexagon ring with six carbon atoms.

Is C6H6 harmful to humans?

Yes, it is carcinogenic.

Is benzene a solvent?

Yes, used in gasoline, car emissions, and cigarette smoke.

What happens if you smell benzene?

Short-term exposure causes drowsiness, dizziness, headaches, and respiratory irritation; high levels can cause unconsciousness.