Overview of Topic- Anomalous Properties of Lithium
The deviation of an element’s attributes and behavior from its regular or normal behavior is referred to as anomalous behavior.
The following are the reasons for this:
Its atom and ion are extremely tiny.
High polarising power
Lithium’s peculiar behavior is as follows:
Lithium is harder than the other metals in its group.
Its melting and boiling points are higher than those of other metals.
It has the least amount of reactivity.
It is the most powerful reducing agent.
LiCl is deliquescent, unlike other metals, and exists as LiCl.2H2.
Li+ ion polarises water molecules more readily than other alkali metals in its group, hence lithium salts attract water molecules and exist as crystallization water (2H2O). Other alkali metal ions normally form anhydrous salts as the polarising power of the ions decreases with increasing ion size.
When lithium reacts with ethyne, it does not generate ethynide.
Lithium oxide (Li2O) is formed when lithium nitrate is heated.
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