BlogIIT-JEEHalogenation of Alkanes

Halogenation of Alkanes

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    Introduction

    Halogenation is a type of chemical reaction in the addition of one or more halogens to a substance or molecule. The stoichiometry and route of halogenation are regulated by the functional groups and structural properties of the organic substrate and the unique halogen.

    A brief outline

    When an alkane is halogenated, one or more halogen atoms are swapped for hydrogen atoms, resulting in a hydrocarbon derivative. Alkanes are often unreactive chemicals and they are non-polar and lack functional groups where reactions can take place.

    Important concepts

    The halogenation of alkanes is an example of a substitution reaction, which is a common type of reaction in organic chemistry. A substitution reaction occurs when a small component of a responding molecule replaces an atom or even the atom’s group on a hydrocarbon or even its derivative.

    The replacement of a single halogen atom for one of the hydrogen atoms in an alkane has a generic equation.

    Qualities of alkane halogenation.

    1. An alkane is addressed by the image R-H. In the present circumstance, R represents an alkyl bunch. At the point when a hydrogen iota is added to an alkyl bunch, the alkyl gathering’s guardian hydrocarbon is shaped.
    2. On the item side, the image R-X means the conventional equation for a halogenated alkane. A halogen iota is addressed by the letter X.
    3. Placing reaction conditions on the equation arrow that divides reactants and products is a good way to keep track of them. The existence of heat or light is required for the halogenation of an alkane.

    The homolytic breakdown of a Cl-Cl bond to produce two Cl atoms is the first step. The freshly produced methyl radical removes a Cl atom from a chlorine molecule, resulting in chloromethane and the formation of another Cl atom. Chlorine, chloromethane, and ethane are the termination products.

    Alkanes can be functionalized using the free-radical halogenation technique. The count of identical C-H bonds, which is prevalent in all but the basic alkanes, is a major constraint of radical halogenation, making selective reactions difficult to execute.

    Significance of halogenation of alkanes in IIT JEE exam

    Halogenation of alkanes is a type of organic chemistry that studies specific reactions. This topic carries a 6.33 per cent weighting in the IIT JEE exam. All three primary units of chemistry – organic, inorganic, and physical chemistry – were given similar weightage in terms of high weightage chapters for JEE.

    FAQs

    What is the process of halogenation?

    Halogenation is a chemical process that occurs when one or more halogens are added to a material.

    What is the essence of the halogenation of alkanes mechanism?

    The reaction of a halogen with an alkane in the presence of ultraviolet (UV) light or heat results in the creation of a haloalkane (alkyl halide).

    What happens when alkanes react?

    Alkanes are subjected to a limited number of reactions. Combustion and halogenation are the two reactions that further imports undergo

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