Chemistry(a) Following are the transition metal ions of 3d series:Ti4+, V2+, Mn3+, Cr3+ (Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24) Answer the following:(i) Which ion is most stable in an aqueous solution and why?(ii) Which ion is a strong oxidising agent and why?(iii) Which ion is colourless and why?(b) Complete the following equations:(i) 2MnO4−+16H++5S2−⟶(ii) KMnO4⟶ heat 

(a) Following are the transition metal ions of 3d series:
Ti4+, V2+, Mn3+, Cr3+ (Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24) Answer the following:
(i) Which ion is most stable in an aqueous solution and why?
(ii) Which ion is a strong oxidising agent and why?
(iii) Which ion is colourless and why?
(b) Complete the following equations:
(i) 2MnO4+16H++5S2
(ii) KMnO4 heat 

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    Solution:

    (a)
    (i) V2+ and Cr3+ are most stable as they both have the [Ar]3d3 or 𝑡32g stable electronic configuration.
    (ii) Mn3+ ions are the strongest oxidising agent in the aqueous solution because after converting to Mn2+ they get stable half-filled d5 electronic configuration.
    (iii) Ti4+ has no electron in d orbital. No d-d transition is possible in this case. Therefore, it is colourless.
    (b)
    (i) 2MnO4+16H++5S22Mn2++8H2O+5S
    (ii) 2KMnO4 heat K2MnO4+MnO2+O2

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