ChemistryAmong the following compounds, which one has the shortest C – Cl bond?

Among the following compounds, which one has the shortest C – Cl bond?

A
B
C
D

Solution:

In ${CH}_{2} = CH - {Cl}_{. .}^{. .} :$ , lone pair of Cl and double bond are in conjugation with each other. Therefore, the molecule exhibit resonance and a partial double bond character develops between C-Cl. Therefore, the bond length of C-Cl in fourth molecule is the shortest.

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