Table of Contents
Potential difference plays a crucial role in the flow of electric current. The definition of electric potential states that the amount of work required to move a positive unit charge from infinity to a point is the potential of that point. When there is a difference between the potential of two points, a potential gradient is formed, which allows current to flow.
What is Potential Difference?
Potential difference refers to the amount of work required to move a unit charge from one point to another. One point will have a higher potential, while the other will have a lower potential. Work must be done when moving a positive charge from a point of lower potential to a point of higher potential.
Unit of Potential Difference
The unit of potential difference is the volt (V). One volt is defined as the potential difference between two points in a circuit when one joule of energy is used to move one coulomb of charge between those two points.
Mathematically, it is expressed as:
1 V = 1 Joule / 1 Coulomb
This relationship illustrates that a potential difference of 1 volt exists when 1 joule of work is done to move 1 coulomb of charge between two points in an electric field.
Potential difference as a scalar quantity
Potential difference is considered a scalar quantity because it only has magnitude and no directional property. Unlike vector quantities, which require both magnitude and direction (like force or velocity), potential difference is concerned solely with the difference in electric potential energy between two points, and it does not involve any inherent directionality.
In an electric circuit, potential difference tells us how much energy per charge is being used or provided, but it doesn’t need a directional component to describe this; it simply measures the difference in energy levels (in volts) across two points. Therefore, it can be added or subtracted directly without considering direction, making it scalar by nature.
Dimensional Formula of Potential Difference
From the definition discussed above, the potential difference can be written as :
ΔV= Δ W/Q
Q = electric charge
W = work done
So, dimension of potential difference= dimension of work done / dimension of electric charge.
W= F.S
So, dimension of W = [MLT-2] x [L] = [ML2T-2]
So, dimension of ΔV = [ML2T-2] / [IT] = [MI-1L2T-3]
So, the dimension of potential difference is [MI-1L2T-3]
Potential Difference and EMF of a Cell
The potential difference between the electrodes of a Galvanic cell is called the cell potential. It is defined as the difference between the reduction potentials of the anode and cathode, measured in volts.
When no current is drawn from the cell, the potential difference is termed the EMF (electromotive force). The EMF is positive and is calculated as the difference between the potentials of the half-cell on the right and the half-cell on the left.
EMF Formula:
Ecell = Eright – Eleft ….. (eq1)
Cell Reaction:
In this example, the copper electrode acts as the anode, and the silver electrode is the cathode. The overall reaction is:
Cu (s) + 2Ag+ (aq) → Cu2+ (aq) + 2 Ag (s) ……. (eq2)
Here, (s) indicates the solid state of the electrode, and (aq) represents the ions dissolved in water.
Half-cell reactions
- Cathode (reduction): 2Ag+(aq)+2e−→2Ag(s)
- Anode (oxidation): Cu(s)→Cu2+(aq)+2e−
The overall cell reaction is the summation of these two half-cell reactions.
Difference between Cell Potential and EMF
Cell Potential | EMF (Electromotive Force) |
---|---|
The potential difference between two electrodes when current is flowing through the cell. | The maximum potential difference between two electrodes when no current is flowing (open circuit condition). |
Measured when the circuit is closed and the cell is in use. | Measured when the circuit is open, and no current is flowing. |
Affected by current, internal resistance, and external load. | Independent of current and load, remains constant. |
Usually lower than EMF due to internal resistance and energy losses. | Represents the maximum theoretical voltage of the cell. |
Refers to the actual voltage output during operation. | Refers to the theoretical maximum voltage under ideal conditions (no load). |
The voltage measured across a battery powering a device. | The open-circuit voltage of a battery without any load attached. |