ChemistryFor a cell reaction involving a two-electron change, the standard e.m.f. of the cell is found to be 0.295 V at 25 0 C. The equilibrium constant of the reaction at 25 0 C will be

For a cell reaction involving a two-electron change, the standard e.m.f. of the cell is found  to be 0.295 V at 250C. The equilibrium constant of the reaction at 250C will be   

  1. A
    1 × 10–10
  2. B
    29.5 × 10–2
  3. C
    10
  4. D
    1 × 1010

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    Solution:

    From Thermodynamics ΔGo=-2.303RTlogKc

    ΔGO=-nFEo

    Equating both and simplifying

    logKc=nFEo2.303RT=nEo0.0591=2×0.2950.0591=10

    Kc=1010

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